Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000
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چکیده
منابع مشابه
Complete furanics-sugar separations with metal-organic framework NU-1000.
Metal-organic framework NU-1000 selectively adsorbs furanics, while completely excluding the adsorption of monomeric sugars from the same aqueous mixture. The highly refined degree of molecular recognition exhibited by NU-1000 is exemplified with it selectively adsorbing 5-hydroxymethylfurfural, even in the presence of up to a 300-fold excess of glucose in solution.
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Metal-organic frameworks (MOFs) constructed from Zr6-based nodes have recently received considerable attention given their exceptional thermal, chemical, and mechanical stability. Because of this, the structural diversity of Zr6-based MOFs has expanded considerably and in turn given rise to difficulty in their precise characterization. In particular it has been difficult to assign where protons...
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A series of metallosalen-based metal-organic frameworks (MOFs) have been prepared by the post-synthesis modification of Mn(III)SO-MOF, a Mn(3+)(salen)-based MOF. Treatment of Mn(III)SO-MOF with H(2)O(2) effects the removal of the Mn(3+) ions from the salen struts, which can then be remetalated with a variety of metal precursors to form isostructural MSO-MOF materials. The presence of the new me...
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A mesoporous metal-organic framework possessing permanent porosity has been synthesized and characterized for the first time.
متن کاملHighly mesoporous metal–organic framework assembled in a switchable solvent
The mesoporous metal-organic frameworks are a family of materials that have pore sizes ranging from 2 to 50 nm, which have shown promising applications in catalysis, adsorption, chemical sensing and so on. The preparation of mesoporous metal-organic frameworks usually needs the supramolecular or cooperative template strategy. Here we report the template-free assembly of mesoporous metal-organic...
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ژورنال
عنوان ژورنال: Nature Protocols
سال: 2015
ISSN: 1754-2189,1750-2799
DOI: 10.1038/nprot.2016.001